Application of MOF Material Modification Strategy in Electrolysis of Water

Authors

  • Jiachao Yan

DOI:

https://doi.org/10.6919/ICJE.202603_12(3).0005

Keywords:

MOFs Materials; Electrolytic Water; Material Modification.

Abstract

As a key component of sustainable hydrogen production technology, electrocatalytic water decomposition has promoted the development of various catalysts. Metal organic frameworks (MOFs) have become potential candidate catalysts for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). However, MOFs materials face challenges related to stability, conductivity and scalability. This review systematically summarizes the basic chemical reactions and reaction mechanisms of electrolytic water reaction, deeply analyzes the application of MOFs materials in electrolytic water, and finally puts forward suggestions for the structural modification strategy of MOFs materials in the future.

Downloads

Download data is not yet available.

References

[1] M.P. Browne, F. Novotny´, C.L. Manzanares Palenzuela, J. Šturala, Z. Sofer, M.Pumera. 2H and 2H/1T-Transition Metal Dichalcogenide Films Prepared via Powderless Gas Deposition for the Hydrogen Evolution Reaction[J]. ACS Sustain, Chem. Eng, 2019, 7 (19): 16440-16449.

[2] L. Ouyang, J. Jiang, K. Chen, M. Zhu, Z. Liu. Hydrogen Production via Hydrolysis and Alcoholysis of Light Metal-Based Materials[J]. A Review, Nanomicro Lett, 2021, 13 (1) :134.

[3] Hyeonjung Jung, Seokhyun Choung, Jeong Woo Han. Design principles of noble metal-free electrocatalysts for hydrogen production in alkaline media: combining theory and experiment[J]. Nanoscale Advances, 2021, 3(24): 6797-6826.

[4] James D. Blakemore, Robert H. Crabtree, Gary W. Brudvig. Molecular Catalysts for Water Oxidation[J]. Chem. Rev, 2015, 115:12974−13005.

[5] Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., et al. Water electrolysis: from textbook knowledge to the latest scientific strategies and industrial developments[J]. Chem. Soc. Rev, 2021, 51:4583-4762.

[6] Lu, X. F., et al. Metal–organic frameworks based electrocatalysts for the oxygen reduction reaction[J]. Angew. Chem. Int. Ed, 2019, 59:4634-4650.

[7] Zand, Z., Mohammadi, M. R., Sologubenko, A. S., Handschin, S., Bagheri, R., Chernev, P., et al. Oxygen evolution reaction by silicate-stabilized manganese oxide[J]. ACS Applied Energy Materials, 2023, 6(3):1702-1713.

[8] Camillo Spöri, Pascal Briois, et al. Experimental Activity Descriptors for Iridium-Based Catalysts for the Electrochemical Oxygen Evolution Reaction (OER)[J]. ACS Catal, 2019, 9, 8, 6653-6663.

[9] Sengeni Anantharaj, et al. “The Fe Effect”: A review unveiling the critical roles of Fe in enhancing OER activity of Ni and Co based catalysts[J]. Nano Energy, 2021, 80, 105514.

[10] Chunhua Yang, Zhao-Di Yang, et al. Theory-Driven Design and Targeting Synthesis of a Highly-Conjugated Basal-Plane 2D Covalent Organic Framework for Metal-Free Electrocatalytic OER[J]. ACS Energy Lett, 2019, 4, 9, 2251-2258.

[11] Zhanwu Lei, Tanyuan Wang, et al. Recent Progress in Electrocatalysts for Acidic Water Oxidation[J]. Advanced Energy Materials, 2020, 10(23): 2000478.

[12] KE EBAŞ A, KAYFECI M, BAYAT M. Chapter 9-Electrochemical hydrogen generation[M]. Solar Hydrogen Production. Academic Press, 2019: 299-317.

[13] Y. Matsumoto, E. Sato. Electrocatalytic properties of transition metal oxides for oxygen evolution reaction[J]. Materials Chemistry and Physics, 1986, 14(5): 397-426.

[14] Congling Hu, et al. Recent progress made in the mechanism comprehension and design of electrocatalysts for alkaline water splitting[J]. Energy Environ Sci, 2019, 12, 2620.

[15] Zhi Wen Chen, Jian Li, Pengfei Ou, et al. Unusual Sabatier principle on high entropy alloy catalysts for hydrogen evolution reactions[J]. Nature Communications, 2024, 15, 359.

[16] Yujia He, Wei Liu, Jingquan Liu. MOF-based/derived catalysts for electrochemical overall water splitting[J]. Journal of Colloid And Interface Science, 2024, 661, 409-435.

[17] Shankar Naik Shreyanka, Jayaraman Theerthagiri, Seung Jun Lee, et al. Multiscale design of 3D metal–organic frameworks (M−BTC, M: Cu, Co, Ni) via PLAL enabling bifunctional electrocatalysts for robust overall water splitting[J]. 2022, 446, 2, 137045.

[18] Qianqian Ji, Yuan Kong, Chao Wang, et al. Lattice Strain Induced by Linker Scission in Metal-Organic Framework Nanosheets for Oxygen Evolution Reaction[J]. ACS Catalysis, 2020, 10, 10, 5691-5697.

[19] Jun-Wei Ji, Li-Jing Zhang, et al. Ligand doping engineering induced robust internal electric field in MOFs/BiVO4 photoanode for water splitting[J]. Chemical Engineering Journal, 2024, 484, 149597.

[20] Fanpeng Cheng, Xianyun Peng, Lingzi Hu, et al. Accelerated water activation and stabilized metal-organic framework via constructing triangular active-regions for ampere-level current density hydrogen production[J]. Nature Communications, 2022, 13, 6486.

[21] Yuanyuan Guo, Qi Huang, Junyang Ding, et al. CoMo carbide/nitride from bimetallic MOF precursors for enhanced OER performance[J]. International Journal of Hydrogen Energy, 2021, 46(43): 22268-22276.

[22] Mahesh Burud, Supriya A. Patil, Vidhya Jadhav, et al. Synergistic Effect of CoFe Bimetallic MOF for Efficient Electrocatalytic OER in Alkaline Media[J]. Energy & Fuels, 2025, 39, 28, 13648-13657.

[23] Lu Bai, Xin Wang, Minghua Huang, et al. Fabrication of MOF-on-MOF derived heterostructure on carbon nanofibers towards highly efficient electrocatalytic water splitting[J]. Journal of Alloys and Compounds, 2026, 1056, 186621.

[24] Kaihang Yue, Ruihu Lu, Mingbin Gao, et al. Polyoxometalated metal-organic framework superstructure for stable water oxidation[J]. Science, 2025, 388(6745): 430-436.

Downloads

Published

2026-03-19

Issue

Section

Articles

How to Cite

Yan, J. (2026). Application of MOF Material Modification Strategy in Electrolysis of Water. International Core Journal of Engineering, 12(3), 46-52. https://doi.org/10.6919/ICJE.202603_12(3).0005