Research Progress on Warm-Mix and Odor-Reduction Technologies for CR/SBS Composite Modified Asphalt
DOI:
https://doi.org/10.6919/ICJE.202603_12(3).0030Keywords:
CR/SBS Composite Modified Asphalt; Warm-Mix Technology; Odor-Reduction Technology; VOCs; Fume Emission Reduction.Abstract
SBS-modified asphalt has been widely used in the construction of high-grade highways because of its excellent high- and low-temperature performance, fatigue resistance, and durability. However, SBS-modified asphalt still suffers from problems such as relatively high cost and insufficient storage stability. Crumb rubber (CR)-modified asphalt can realize the resource utilization of solid waste and shows certain advantages in improving asphalt elasticity and high-temperature performance, but it also has shortcomings such as poor high-temperature storage stability, high construction viscosity, and susceptibility to phase separation. To simultaneously satisfy the requirements of pavement performance, storage stability, and resource utilization, CR/SBS composite modification has gradually become a research focus. Existing studies have shown that the composite modification of CR and SBS can significantly improve the high-temperature rutting resistance, low-temperature cracking resistance, and fatigue performance of asphalt and asphalt mixtures through the synergistic effects of rubber elasticity and polymer network structure. However, it also leads to problems such as increased system viscosity, elevated construction temperature, and increased emissions of volatile organic compounds (VOCs). Warm-mix technology can reduce energy consumption and emissions by lowering construction temperature, while odor-reduction technology can suppress the release of asphalt fumes and hazardous volatile substances at the source. This paper systematically reviews the domestic and international research status of CR/SBS composite modified asphalt, warm-mix technology, and asphalt odor-reduction technology, with emphasis on the performance enhancement mechanisms of multicomponent composite systems, VOC emission reduction pathways, and existing key issues. The prospects for the synergistic application of warm-mix additives and odor-reducing agents in CR/SBS composite modified systems are also discussed, with the aim of providing a reference for the development and engineering application of environmentally friendly, high-performance composite modified asphalt materials.
Downloads
References
[1] Khan I, Bilal M, Khaliq W, et al. Evaluating the dynamic response and phase angle behavior of SBS-modified asphalt mixtures for enhanced pavement performance[J]. Scientific Reports, 2024,14(1).
[2] Wei Y, Liu Y, Muhammad Y, et al. Study on the properties of GNPs/PS and GNPs/ODA composites incorporated SBS modified asphalt after short-term and long-term aging[J]. Construction and Building Materials, 2020,261:119682.
[3] Zhou T, Kabir S F, Cao L, et al. Comparing effects of physisorption and chemisorption of bio-oil onto rubber particles in asphalt[J]. Journal of cleaner production, 2020,273:123112.
[4] Liang M, Xin X, Fan W Y, et al. Investigation of the rheological properties and storage stability of CR/SBS modified asphalt[J]. Construction and Building Materials, 2015,74:235-240.
[5] Qian C, Fan W, Liang M, et al. Rheological properties, storage stability and morphology of CR/SBS composite modified asphalt by high-cured method[J]. Construction and Building Materials, 2018,193:312-322.
[6] Kök B V, Yilmaz M, Geçkil A. Evaluation of Low-Temperature and Elastic Properties of Crumb Rubber– and SBS-Modified Bitumen and Mixtures[J]. Journal of Materials in Civil Engineering, 2013,25(2):257-265.
[7] Dong F, Yu X, Liu S, et al. Rheological behaviors and microstructure of SBS/CR composite modified hard asphalt[J]. Construction and Building Materials, 2016,115:285-293.
[8] Borinelli J B, Portillo-Estrada M, Costa J O, et al. Emission reduction agents: A solution to inhibit the emission of harmful volatile organic compounds from crumb rubber modified bitumen[J]. Construction and Building Materials, 2024,411.
[9] Wang Z P, Li H, Jia M, et al. Emission Risk and Inhibition Technology of Asphalt Fume from Crumb Rubber Modified Asphalt[J]. Sustainability, 2024,16(20).
[10] Xie J, Luo H, Zhao X, et al. Harmful emissions of rubber asphalt at high temperatures: A review[J]. Materials Express, 2023,13(2):206-221.
[11] Rubio M C, Martínez G, Baena L, et al. Warm mix asphalt: an overview[J]. Journal of Cleaner Production, 2012,24:76-84.
[12] Xiao Y, Wan M, Jenkins K J, et al. Using Activated Carbon to Reduce the Volatile Organic Compounds from Bituminous Materials[J]. Journal of Materials in Civil Engineering, 2017,29(10):4017166.
[13] Wang Z H, Shao J, Song L, et al. Preparation and performance evaluation of SBS/crumb rubber composite modified Xinjiang asphalt[J]. Journal of Chang'an University (Natural Science Edition), 2023, 43(2): 1-15.
[14] Shang H F, Fan L, Shen Q J, et al. Study on preparation and properties of CR/SBS composite modified asphalt based on orthogonal test[J]. China Adhesives, 2025, 34(8): 23-31.
[15] Yang Y Q, Kang B D, Guo H D, et al. Short-term aging performance of activated crumb rubber/SBS composite modified asphalt[J]. Journal of Chang'an University (Natural Science Edition), 2021, 41(5): 23-33.
[16] Li Q X. Study on properties of micro-nano rubber powder/SBS composite modified high-viscosity asphalt and its mixture[J]. Sichuan Cement, 2025(10): 253-254.
[17] Song L, Wang Z H, Shu C, et al. Research progress and performance evaluation of SBS/rubber powder composite modified asphalt[J]. China Journal of Highway and Transport, 2021, 34(10): 17-33.
[18] Behnood A, Olek J. Rheological properties of asphalt binders modified with styrene-butadiene-styrene (SBS), ground tire rubber (GTR), or polyphosphoric acid (PPA)[J]. Construction and Building Materials, 2017,151:464-478.
[19] Ye X Q, Zou X L, Dong Q. Rheological analysis of pavement performance of styrene-butadiene-styrene block copolymer-modified rubber powder composite modified asphalt[J]. Science Technology and Engineering, 2021, 21(2): 758-763.
[20] Lee S, Lee M, Mazumder M, et al. Evaluation of High-Performance Asphalt Binders Modified with SBS, SIS, and GTR[J]. Advances in Civil Engineering, 2019,2019(2019):1-11.
[21] Peng J X, Zhang D M, Liu B. Experimental study on viscoelastic properties of rubber powder and SBS composite modified asphalt[J]. Highway Engineering, 2022, 47(3): 131-136.
[22] Li L D, Wang L, Xu W J, et al. Evaluation of low-temperature viscoelastic properties of crumb rubber-SBS composite modified asphalt[J]. Plastics Science and Technology, 2025, 53(5): 66-73.
[23] Ameri M, Reza Seif M, Abbasi M, et al. Viscoelastic fatigue resistance of asphalt binders modified with crumb rubber and styrene butadiene polymer[J]. Petroleum Science and Technology, 2017,35(1):30-36.
[24] Yalikun N, Yu S L, Yang H R, et al. Preparation and performance study of oxidized CR/SBS composite modified asphalt[J]. Journal of Environmental Chemical Engineering, 2025,13(3).
[25] Ma F, Wu D, Fu Z, et al. Pavement performance of SBS/waste rubber powder composite modified asphalt and mixture[J]. Applied Chemical Industry, 2022, 51(4): 937-941.
[26] Rubio M C, Martínez G, Baena L, et al. Warm mix asphalt: an overview[J]. Journal of Cleaner Production, 2012,24:76-84.
[27] Sukhija M, Saboo N. A comprehensive review of warm mix asphalt mixtures-laboratory to field[J]. Construction and Building Materials, 2021,274:121781.
[28] Qin Q, Farrar M J, Pauli A T, et al. Morphology, thermal analysis and rheology of Sasobit modified warm mix asphalt binders[J]. Fuel, 2014,115:416-425.
[29] Roja K L, Padmarekha A, Krishnan J M. Rheological Investigations on Warm Mix Asphalt Binders at High and Intermediate Temperature Ranges[J]. Journal of Materials in Civil Engineering, 2018,30(4).
[30] Caputo P, Abe A A, Loise V, et al. The Role of Additives in Warm Mix Asphalt Technology: An Insight into Their Mechanisms of Improving an Emerging Technology[J]. Nanomaterials, 2020,10(6).
[31] Kakar M R, Hamzah M O, Akhtar M N, et al. Evaluating the Surface Free Energy and Moisture Sensitivity of Warm Mix Asphalt Binders Using Dynamic Contact Angle[J]. Advances in Civil Engineering, 2019,2019.
[32] Gao J, Yan K, He W, et al. High temperature performance of asphalt modified with Sasobit and Deurex[J]. Construction and Building Materials, 2018,164:783-791.
[33] Pouranian M R, Notani M A, Tabesh M T, et al. Rheological and environmental characteristics of crumb rubber asphalt binders containing non-foaming warm mix asphalt additives[J]. Construction and Building Materials, 2020,238:117707.
[34] Oliveira J, Silva H, Abreu L, et al. Use of a warm mix asphalt additive to reduce the production temperatures and to improve the performance of asphalt rubber mixtures[J]. Journal of Cleaner Production, 2013,41:15-22.
[35] Yang X, You Z P, Hasan M, et al. Environmental and mechanical performance of crumb rubber modified warm mix asphalt using Evotherm[J]. Journal of Cleaner Production, 2017,159:346-358.
[36] Dinis-Almeida M, Afonso M L. Warm Mix Recycled Asphalt – a sustainable solution[J]. Journal of Cleaner Production, 2015,107:310-316.
[37] Almeida-Costa A, Benta A. Economic and environmental impact study of warm mix asphalt compared to hot mix asphalt[J]. Journal of Cleaner Production, 2016,112:2308-2317.
[38] Chen Z X, Yang Q, Zhang C H, et al. Application of warm mix asphalt technology in winter construction[J]. Highway, 2016, 61(4): 47-50.
[39] Hamzah M O, Jamshidi A, Shahadan Z. Evaluation of the potential of Sasobit® to reduce required heat energy and CO2 emission in the asphalt industry[J]. Journal of Cleaner Production, 2010,18(18):1859-1865.
[40] He L, He Z Y, Ling T Q, et al. Study on construction workability of warm mix rubber asphalt mixture[J]. Journal of Functional Materials, 2015, 46(20): 20102-20107.
[41] Ji J, Dong Y, Yang Y Q, et al. Effects of different warm mix agents on properties of rubber asphalt[J]. Journal of China University of Petroleum (Edition of Natural Science), 2020, 44(6): 133-140.
[42] Gao R, Zhao L. Water stability of warm mix rubber modified asphalt based on AFM technology[J]. Bulletin of the Chinese Ceramic Society, 2018, 37(12): 4045-4049.
[43] Yu H Y, Zhang Z, Deng Y H, et al. Modification mechanism of warm mix rubberized asphalt based on layer-by-layer stripping test[J]. Journal of South China University of Technology (Natural Science Edition), 2024, 52(8): 126-137.
[44] Randem B G, Ulvestad B, Burstyn I, et al. Respiratory symptoms and airflow limitation in asphalt workers: Table 1[J]. Occupational and Environmental Medicine, 2004,61(4):367-369.
[45] Schreiner C A. Review of mechanistic studies relevant to the potential carcinogenicity of asphalts[J]. Regulatory Toxicology and Pharmacology, 2011,59(2):270-284.
[46] Li Y, Shen J, Wang Y G, et al. Research progress on composition of petroleum asphalt fume and smoke suppression technology[J]. Applied Chemical Industry, 2023, 52(1): 256-260.
[47] Zhu H Z, Su C L, Tang N P, et al. Sampling and quantitative analysis method for emissions from crumb rubber modified asphalt[J]. Journal of Jilin University (Engineering and Technology Edition), 2024, 54(10): 2922-2929.
[48] Tang N P, Zhang Z Y, Dong R K, et al. Emission behavior of crumb rubber modified asphalt in the production process[J]. Journal OF Cleaner Production, 2022,340.
[49] Liu Y Y, Zhou S, He Z Q, et al. Research progress on detection methods and suppression measures of asphalt fumes[J]. Chemical Industry and Engineering Progress, 2025, 44(3): 1632-1650.
[50] Mo J Q. Determination of asphalt fume in air by ultraviolet spectrophotometry[J]. Physical Testing and Chemical Analysis (Part B: Chemical Analysis), 2014, 50(4): 498-499.
[51] Li N, Jiang Q, Wang F, et al. Emission behavior, environmental impact and priority-controlled pollutants assessment of volatile organic compounds (VOCs) during asphalt pavement construction based on laboratory experiment[J]. Journal of Hazardous Materials, 2020,398:122904.
[52] Espinoza J, Medina C, Calabi-Floody A, et al. Evaluation of Reductions in Fume Emissions (VOCs and SVOCs) from Warm Mix Asphalt Incorporating Natural Zeolite and Reclaimed Asphalt Pavement for Sustainable Pavements: Sustainability[Z]. 2020: 12, 9546.
[53] Sharma A, Lee B K. A novel nanocomposite of Ca(OH)2-incorporated zeolite as an additive to reduce atmospheric emissions of PM and VOCs during asphalt production[J]. Environmental Science Nano, 2017,4(3):613-624.
[54] Long Y S, Wu S P, Xiao Y, et al. Study on volatilization law of VOCs from asphalt based on PY-GC-MS[J]. Journal of Wuhan University of Technology (Transportation Science & Engineering), 2018, 42(1): 1-6.
[55] Dong Q K. Research on VOCs emission assessment model of hot mix asphalt pavement in whole life cycle[D]. Wuhan: Wuhan University of Technology, 2021.
[56] Zhang R. Study on escape behavior and suppression of organic emissions from asphalt materials[D]. Chongqing: Chongqing Jiaotong University, 2023.
[57] Hu Y C, Liu A G, Liu Q H, et al. Analysis of flame retardant and smoke suppression performance of modified asphalt based on thermogravimetry-mass spectrometry[J]. Journal of Wuhan University of Technology (Transportation Science & Engineering), 2022, 46(4): 707-712.
[58] Yang X L, Wang G C, Rong H L, et al. Review of fume-generation mechanism, test methods, and fume suppressants of asphalt materials[J]. Journal of Cleaner Production, 2022,347.
[59] Li S, Liu Q, Wang H, et al. Effect of kaolin and sepiolite on fume emissions of rubber modified asphalt[J]. Construction and Building Materials, 2024,416:135276.
[60] Yang X, Shen A, Su Y, et al. Effects of alumina trihydrate (ATH) and organic montmorillonite (OMMT) on asphalt fume emission and flame retardancy properties of SBS-modified asphalt[J]. Construction and Building Materials, 2020,236:117576.
[61] Lv Y, Wu S, Li N, et al. Performance and VOCs emission inhibition of environmentally friendly rubber modified asphalt with UiO-66 MOFs[J]. Journal of Cleaner Production, 2023,385:135633.
[62] Duan H, Liu Q, He Y, et al. Enhanced asphalt fume suppression through cellulose- and lignin-rich biochar: A structure-property relationship[J]. Construction and Building Materials, 2025,495:143655.
[63] Xu Y L, Yang X L, Zhou J S, et al. Asphalt fume composition of warm mix asphalt and smoke suppression performance of warm mix agent[J]. Journal of Jilin University (Engineering and Technology Edition), 2024, 54(6): 1701-1707.
Downloads
Published
Issue
Section
License
Copyright (c) 2026 International Core Journal of Engineering

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.




